| 1 | Jankovic, Jelena (SRB) | | | | Bye |
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| Q | Jidkova, Alina (RUS) | 7/6(6) 6/1 | | Q | Stevenson, Alexandra (USA) |
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| | Sequera, Milagros (VEN) | 6/4 4/6 7/5 | | | Rezai, Aravane (FRA) |
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| | Rodionova, Anastasia (RUS) | 6/4 1/0 Ret'd | | 15 | Cibulkova, Dominika (SVK) |
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| 9 | Zvonareva, Vera (RUS) | 6/2 6/2 | | Q | Chuang, Chia-Jung (TPE) |
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| | Puchkova, Olga (RUS) | 4/6 7/5 6/0 | | | Ruano Pascual, Virginia (ESP) |
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| | Salerni, Ma. Emilia (ARG) | 7/5 6/4 | | | Dellacqua, Casey (AUS) |
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| | Bye | | | 6 | Bartoli, Marion (FRA) |
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| 4 | Dementieva, Elena (RUS) | | | | Bye |
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| | Craybas, Jill (USA) | 6/2 6/2 | | Q | Lepchenko, Varvara (USA) |
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| W | Rolle, Ahsha (USA) | 2/6 7/6(1) 6/2 | | Q | Sun, Tiantian (CHN) |
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| Q | Scheepers, Chanelle (RSA) | 6/1 6/0 | | 13 | Azarenka, Victoria (BLR) |
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| 11 | Radwanska, Agnieszka (POL) | 6/4 4/6 6/3 | | | Domachowska, Marta (POL) |
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| | Gallovits, Edina (ROU) | 6/3 2/0 Ret'd | | | Shaughnessy, Meghann (USA) |
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| | Vesnina, Elena (RUS) | 6/3 6/2 | | | Govortsova, Olga (BLR) |
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| | Bye | | | 7 | Schnyder, Patty (SUI) |
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| 8 | Safina, Dinara (RUS) | | | | Bye |
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| Q | Wozniak, Aleksandra (CAN) | 6/1 6/1 | | | Dominguez Lino, Lourdes (ESP) |
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| | Morita, Ayumi (JPN) | 6/4 6/1 | | | Sugiyama, Ai (JPN) |
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| | Fedak, Yuliana (UKR) | 6/0 7/6(4) | | 10 | Szavay, Agnes (HUN) |
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| 16 | Krajicek, Michaella (NED) | 6/3 3/6 6/4 | | | Cornet, Alize (FRA) |
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| | Ditty, Julie (USA) | 6/2 6/3 | | | Errani, Sara (ITA) |
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| | Cirstea, Sorana (ROU) | 6/7(5) 7/5 6/1 | | W | King, Vania (USA) |
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| | Bye | | | 3 | Chakvetadze, Anna (RUS) |
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| 5 | Williams, Serena (USA) | | | | Bye |
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| | Dulko, Gisela (ARG) | 6/2 6/3 | | | Molik, Alicia (AUS) |
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| | Chan, Yung-Jan (TPE) | 6/3 6/2 | | Q | Zahlavova Strycova, Barbora (CZE) |
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| | Bacsinszky, Timea (SUI) | 7/6(4) 6/3 | | 12 | Srebotnik, Katarina (SLO) |
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| 14 | Medina Garrigues, Anabel (ESP) | 4/6 6/0 7/5 | | | Perebiynis, Tatiana (UKR) |
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| L | Schruff, Julia (GER) | 7/6(2) 6/4 | | | Voskoboeva, Galina (RUS) |
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| | Yuan, Meng (CHN) | 6/3 4/6 6/2 | | W | Mattek, Bethanie (USA) |
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| | Bye | | | 2 | Sharapova, Maria (RUS) |
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| Jankovic,J | 7/5 6/0 | | Stevenson,A |
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| Rezai,A | 6/3 6/4 | | Rodionova,A |
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| Zvonareva,V | 6/1 6/0 | | Ruano Pascual,V |
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| Dellacqua,C | 7/5 4/6 6/1 | | Bartoli,M |
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| Dementieva,E | 6/0 6/2 | | Craybas,J |
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| Sun,T | 7/6(4) 6/0 | | Azarenka,V |
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| Radwanska,A | 6/7(7) 6/2 7/5 | | Gallovits,E |
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| Govortsova,O | 7/6(2) 6/0 | | Schnyder,P |
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| Safina,D | 6/1 6/4 | | Dominguez Lino,L |
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| Sugiyama,A | 7/5 3/6 6/4 | | Szavay,A |
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| Cornet,A | 6/3 2/6 6/3 | | Errani,S |
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| Cirstea,S | 6/2 1/6 6/2 | | Chakvetadze,A |
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| Williams,S | 6/3 6/4 | | Dulko,G |
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| Zahlavova Strycova,B | 4/6 6/1 7/5 | | Srebotnik,K |
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| Perebiynis,T | 6/4 6/3 | | Schruff,J |
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| Mattek,B | 6/0 6/0 | | Sharapova,M |
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| Jankovic,J | 6/0 6/2 | | Rodionova,A |
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| Zvonareva,V | 6/4 4/6 6/1 | | Bartoli,M |
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| Dementieva,E | 6/4 7/5 | | Azarenka,V |
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| Radwanska,A | 6/3 6/2 | | Schnyder,P |
|
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| Cornet,A | 6/1 7/5 | | Cirstea,S |
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| Williams,S | 4/6 6/4 6/3 | | Srebotnik,K |
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| Perebiynis,T | 7/5 6/2 | | Sharapova,M |
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| Jankovic,J | 6/2 3/6 6/2 | | Zvonareva,V |
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| Dementieva,E | 6/4 6/4 | | Schnyder,P |
|
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| Williams,S | 7/5 4/6 6/1 | | Sharapova,M |
|
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| Zvonareva,V | 6/3 6/7(2) 6/3 | | Dementieva,E |
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| Cornet,A | 7/5 6/3 | | Williams,S |
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